Tungsten nanowire exhibits a phenomenon called "twinning" that allows it to deform under pressure without breaking, and to regain its shape when the load is removed.
To fully understand how nanomaterials behave, one must also understand the atomic-scale deformation mechanisms that determine their structure and, therefore, their strength and function. Researchers at the University of Pittsburgh, Drexel University and Georgia Tech have engineered a new way to observe and study these mechanisms and, in doing so, have revealed an interesting phenomenon in a well-known material, tungsten. The group is the first to observe atomic-level deformation twinning in body-centered cubic (BCC) tungsten nanocrystals.
The team used high-resolution transmission electron microscope (TEM) and sophisticated computer modeling to make the observation. This work, published in Nature Materials, represents a milestone in the in-situ study of mechanical behaviors of nanomaterials.
Deformation twinning is a type of deformation that, in conjunction with dislocation slip, allows materials to permanently deform without breaking. In the process of twinning, the crystal reorients, which creates a region in the crystal that is a mirror image of the original crystal. Twinning has been observed in large-scale BCC metals and alloys during deformation. However, whether twinning occurs in BCC nanomaterials or not remained unknown.
A series of images captured by transmission electron microscopy show the phenomenon of twinning occurring in tungsten nanowire.
“To gain a deep understanding of deformation in BCC nanomaterials,” Mao said. “We combined atomic-scale imaging and simulations to show that twinning activities dominated for most loading conditions, due to the lack of other shear deformation mechanisms in nanoscale BCC lattices.”
The team chose tungsten as a typical BCC crystal. The most familiar application of tungsten is their use as filaments for light bulbs.
The observation of atomic-scale twinning was made inside a TEM. This kind of study has not been possible in the past, due to difficulties of making BCC samples less than 100 nanometers in size, as required by TEM imaging. Jiangwei Wang, a graduate student at University of Pittsburgh, and Mao, the lead author of the paper, developed a clever way of making the BCC tungsten nanowires. Under a TEM Wang welded together two small pieces of individual nanoscale tungsten crystals to create a wire about 20 nanometers in diameter. This wire was durable enough to stretch and compress while Wang observed the twinning phenomenon in real time using a high-resolution TEM.
Computer models demonstrate the process of twinning in tungsten nanowire.
To better understand the phenomenon observed by Mao and Wang’s team at Pitt, Christopher Weinberger, PhD, an assistant professor in the College of Engineering, developed computer models that show the mechanical behavior of the tungsten nanostructure—at the atomic level. His modeling allowed the team to see the physical factors at play during twinning. This information will help researchers theorize why it occurs in nanoscale tungsten and plot a course for examining this behavior in other BCC materials.
“We’re trying to see if our atomistic-based model behaves in the same way as the tungsten sample used in the experiments, which can then help to explain the mechanisms that allow it to behave that way,” Weinberger said. “Specifically, we’d like to explain why it exhibits this twinning ability as a nanostructure, but not as a bulk metal.”
In concert with Weinberger’s modeling, Ting Zhu, an associate professor of mechanical engineering at Georgia Tech, worked with a graduate student, Zhi Zeng, to conduct advanced computer simulations, using molecular dynamics to study deformation processes in 3-D.
Zhu’s simulation revealed that tungsten’s “smaller is stronger” behavior is not without drawbacks when it comes to application.
“If you reduce the size to the nanometer scale, you can increase strength by several orders or magnitude,” Zhu said. “But the price you pay is a dramatic decrease in the ductility.
We want to increase the strength without compromising the ductility in developing these nanostructured metals and alloys. To reach this objective, we need to understand the controlling deformation mechanisms.”
The twinning mechanism, Mao added, contrasts with the conventional wisdom of dislocation nucleation-controlled plasticity in nanomaterials. The results should motivate further experimental and modeling investigation of deformation mechanisms in nanoscale metals and alloys, ultimately enabling the design of nanostructured materials to fully realize their latent mechanical strength.
"Our discovery of the twinning dominated deformation also opens up possibilities of enhancing ductility by engineering twin structures in nanoscale BCC crystals" Zhu said.