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Publication

TITLE: Nanoengineered Nanofibrous Materials
Series: Nato Science Series II, Mathematics, Physics and Chemistry Volume number: 169
NATO-ASI (PST 979397)
ISBN: Hardbound 1-4020-2548-3; Paperback 1-4020-2549-1; E-Book 1-4020-2550-5

Publisher: Kluwer Academic Book Publishers, Dordrecht, Netherlands (2004)
Editors: Guceri, S.I; Y. Gogotsi, and V. Kuzentsov

Assistant Editor: Jennifer Wright


Chapter 1: Formation of Nanofibers and Nanotubes Production

1.1 “Nanofiber Technology: Bridging the Gap between the Nano and Macro World
F. Ko…………………………………………………………………………….1

1.2 “Mechanism of Carbon Filaments and Nanotubes Formation”
V. Kuznetsov……………………………………………………………….........19

1.3 ‘CCVD Synthesis of Single- and Double-walled Carbon Nanotubes”
E. Flahaut A. Peigney and Ch. Laurent……………………………………...........35

1.4 “Precise Semiconductor, Metal and Hybrid Nanotubes, Nanobelts
and Nanofibers”

V. Prinz……………………………………………………………………….....47

1.5 “Carbon Nanopipettes: Synthesis, Characterization, Properties”
R. C. Mani, M. K. Sunkara , X. Li,and K. Rajan……..……….......………..........65

1.6 “Influence of PLD and CVD Experimental Growth Conditions on Carbon
Film Nanostructure Evolution”

E. Capelli, S. Orlando, G. Mattei, C. Sciletta, , F.Corticelli, and P. Ascarelli… .…75

1.7 “Controlled Growth and Networking of Tapered Carbon Tube Morphologies”
G. Bhimarasetti, M. K. Sunkara, Uschi Graham, C.Suh and K. Rajan.......….........83

1.8 “Carbon Filament Rope Formation”
A. N. Usoltseva, V. L. Kuznetsov, N. A. Rudina, M. Yu. Alekseev
and L. V. Lutsev…........................................................................................…...91

1.9 “Electrospinning of Low Surface Energy-Quaternary Ammonium Salt
Containing Polymers and their Antibacterial Activity”

K. Acatay, E. Simsek, M. Akel and Y. Z. Menceloglu………………………......97

1.10 “On the Mechanism of Single-wall Carbon Nanotube Nucleation in the Arc
and Laser Processes: Why Bimetallic Catalysts Have High Efficiency”

A.V. Krestinin, M.B. Kislov and A.G. Ryabenko..…............................…….......107

1.11 “Production of Boron Nitride by Carbothermal and Mechanochemical
Methods and Nanotube Formation”

H. E. Camurlu, A. Aydogdu, Y. Topkaya and N. Sevinc…….......………..........115

1.12 “Structure and Properties of Silicon Carbide Fibers Depending on Their
Synthesis Conditions”

K. Vyshnyakova and L.N. Perselentseva…………………………………........121

Chapter 2. Physics and Chemistry of Nanofibers

2.1 “Selective Oxidation of HipCO Single Wall Carbon Nanotubes”
S.N. Bokova, E.D. Obraztsova, A.V. Osadchy, H. Kuzmany,
U. Dettlaff-Weglikowska, S.Roth……………………………………………..129

2.2 “Oxygenation of Carbon Nanotubes”
Sefa Dag, S. Çiraci, O. Gülseren, and T. Yildirim…………….………….........135

2.3 “Electronic Structure of Fluorinated Carbon Nanotubes’’
L.G. Bulusheva, A.V. Okotrub, T.A. Duda, E.D. Obraztsova,

A.L. Chuvilin, E.M. Pazhetnov, A.I. Boronin and U. Detlaff-Wegikowska….....143

2.4 “Titanium Coverage on Single-Wall Carbon Nanotubes: Molecular
Dynamics Simulations”

H. Oymak and S. Erkoc...…………………………………………………....151

2.5 “Using Supercritical Water Manipulates the Structures of Porous Materials
and Nano-scale Particles”

J.C. Li, R. Aswani, X.L. Gao, S. King and A.I. Kolesnikov……… ……….....157

2.6 “Functionalization of Carbon Nanotubes: Deformations, Coating, Contacts
and Device Applications”

O. Gulseren.…………………………………………………………… ..….163

2.7 "Towards Fiber-Based Micro and Nanofluidics"
A. Neimark.....................................................................................................173

Chapter 3. Simulation and Modeling

3.1 “Theoretical Models for Nanodevices and Nanomagnets Based
on Carbon Nanotubes”

S. Çiraci,O. Gulseren, S. Dag, E. Durgun and T. Yildirim……….……............181

3.2 “Intimate Relationship between Structural Deformation and Properties
of Singe-Walled Carbon Nanotubes and its Hydrogenated Derivatives”

T. Yildirim, O. Gulseren and S. Ciraci …………………………………….....197

3.3 “Geometry Effect on One-Electron Density of States of Boron
Nitride Nanotubes”

A. Osadchy and E. D. Obraztsova.... ………………………….…………....211

3.4 “Stability of Carbon Nanocapsules: Molecular-Dynamics Simulations”
O.B. Malcioglu, V. Tanriverdi, A. Yimaz and S. Erkoç………………….......217

3.5 “Carbon Nanotube Multi-terminal Junctions: Structures, Properties,
Synthesis and Applications”

L.A.Chernozatonskii and I.V. Ponomarev………………....………………..223

3.6 “Simulation of Carbon Nanotube Junction Formations”
E. Tasci, O.B. Malcioglu and S. Erkoc……...………………………….…..235

3.7 “Stability of Carbon Nanotori”

E. Yazgan, E. Tasçi, O.B. Malcioglu and S. Erkoc..………………….….....239

Chapter 4. Applications

4.1 Biomedical Applications

4.1.1 “Use of High-surface Nanofibrous Materials in Medicine”
S.V. Mikhalovsky, L.I. Mikhalovska, V.G. Nikolaev, V.I Chernyshev,
V.V.Sarnatskaya, K. Bardakhivskaya, A.V. Nikolaev and L.A. akhno……….243

4.1.2 “Nanoscale Engineering of Surfaces. Functionalized Nanoparticles
As Versatile Tools for the Introduction of Biomimetics on Surfaces”
V. P. Shastri , A.M. Lipski, J.C. Sy, W. Znidarsic, H. Choi and I-W. Chen......255

4.1.3 “Catalytic Filamentous Carbons and CFC-Coated Ceramics for
Immobilization of Biologically Active Substances”

G.Kovalenko, D.G. Kuvshinov, O.V.Komova, A.V. Simakov and N.A. Rudina..263

4.1.4 “Hybrid three terminal devices based on modified DNA bases and
Metalloprotein”

R. Rinaldi, G. Maruccio, A. Bramanti, P. Visconti, P.P. Pompa, A. Biasco and
R. Cingolani.......................................................................................................269

4.1.5 “Polyphosphazene Nanofibers for Biomedical Applications:
Preliminary Studies”

C.T. Laurencin and L.S. Nair………………………………...………….........281

4.1.6 “Bionanocomposites Based on Nanocarbon Materials for Culture
Cells Media”

L.Stamatin and I. Stamatin………………………………………………........301

4.2 Nanotube-Based Devices

4.2.1 “Contact-induced Properties of Semiconducting Nanowires and
Their Local Gating”

E. Gallo, A. Anwar and B. Nabet……………………………………….........311

4.2.2 “Bespoke Carbon Nanotube Devices and Structures”
D. C. Cox, R.D. Forrest, P.R. Smith and S.R.P. Silva………………......…....321

4.3 Electronic Applications of Nanotubes and Nanofibers

4.3.1 “Vacuum Electronic Applications of Nano-Carbon Materials”
A. Obraztsov…………………………………………………………............327

4.3.2 “MoS2 Nanotubes as Promising Field Emitter Material”
A. Mrzel, V. Nemanic, M. Umer, B. Zajec, J. Pahor, M. Remskar,
E. Klein and D. Mihailovic.……………………………………………...........339

4.3.3 “X-ray Spectroscopy Characterization of Carbon Nanotubes”
A.V. Okotrub, A.V. Guselnikov and L.G. Bulusheva……………………........347

4.3.4 “Highly Functional Magnetic Nanowires Through Eletrodeposition”
N.Sulitanu………………………………………………….…….......….......361

4.3.5 “Use of Atomic Force Microscope for Nucleic Acids Sensors”
Ü. Dogutan, E. Piþkin and C. Koçum………………………………….........375

4.3.6 “Electrophoretic Deposition of ZnO Thin Film in Aqueous Media
A. Dogan, E. Suvaci, G. Gunkaya and E. Uzgur……………………….........383

4.3.7 “Synthesis and Optical Spectroscopy of Single-Wall Carbon
Nanotubes”

E.D. Obraztsova, M. Fujii, S. Hayashi, A.S. Lobach, I.I. Vlasov
A.V. Khomich, V. Yu. Timoshenko, W. Wenseleers, E.Goovaerts…..........389

4.4 Nanofluidics

4.4.1 “Aqueous Fluids in Carbon Nanotubes: Assisting the Understanding
of Fluid Behavior at the Nanoscale”

A. Yazicioglu, C.M. Megaridis, N. Naguib, H.Ye and Y. Gogotsi………....399

4.4.2 “Dielectrophoretic Assembly and Integration of Nanofluidic Devices”
M. Reigelman, H. Liu, S. Evoy and H. H. Bau…..………………………...407

4.4.3 “Opening Multiwall Carbon Nanotubes with Electron Beam”
H. Ye, N. Nabuib, Y. Gogotsi…..……………………………...…….......415

4.5 Composites

4.5.1 “Molecule Derived Nanomaterials: Chemical Concepts for Composition,
Morphology and Particle Size Control Composites”

S.Mathur.………………………………………………………………..423

4.5.2 “Nanosized Fine Particles and Fibers as Reinforcing Materials
Synthesized from Sepiolite”

AO.Kurt………………………………………………………………....441

4.5.3 “Thermal Conductivity of Particle Reinforced Polymer Composites”
I.H. Tavman……………………………………………………………...449

4.5.4 “Nano particles and Nano Cavities from Conjugated Polymers”
H. Wang, T. Lin and A.Kaynak…………………………………………..457


Chapter 5. Nanomaterials, Nanoparticles, and Nanostructures

5.1 “Nanomaterials for Photonic Applications”
R. Cingolani……………………………………………………………...467

5.2 “Magnetic Nanoscale Particles as Sorbents for Removal of Heavy
Metal Ions”

M. Vaclavikova, S. Jakabsky and S. Hredzak…………………………....479

5.3 “Comparison of a Structural and Dynamical Properties of Liquid Pd, Ag
and the Binary Alloys Modeled by Sutton-Chen”

H. H. Kart, M. Uludoðan, Tahir Çaðýn , and M. Tomak………………....485

5.4 “Hydrothermally Synthesized Nanocrystalline Mn-Zn Ferrites: Synthesis
and Characterization”

D.N. Bakoyannakis, E.A. Deliyanni, K.A. Matis, L. Nalbandian
and V.T. Zaspalis................................................................................…..493

5.5 “Deposition of Sub-micron Ni Droplets on Glass Substrates by a
Combination of Plasma Assisted CVD and PVD”

H. Akbulut, C.Bindal and O.T.Nail……………………………………....499

5.6 “Formation of Fine-Dispersion Fibrous Multilayer Oxide Coatings of
Nano-Dimension Thickness On the Surface of Electroconductive
Si3N4-TiN and Si3N4-TiB2 Ceramics Under Their Electrochemical
Polarization”

V. Lavrenko, M.Desmaison-Brut, V.A.Shvets and J. Desmaiso………….507

5.7 “Formation of High Temperature Nanofibrous Coating Structure
under Magnetron Sputtering of Al-TiCrB2”

A.D.Panasyuk, I.A.Podchernyaeva and V.A.Lavrenko……………….....517

5.8 “Patterning Sub-100 nm Features for Sub-Micron Devices”
H. Kavak………………………………………………………………525

5.9 "Solid and Liquid Properties of Pd-Ni Alloys Using Quantum Sutton-
Chen Many Body Potential"

S.O.Kart, M.Uludogan, T.Cagin and M.Tomak......................................531

Subject Index………………………………………………………….537